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Boron clusters as efficient shuttles for electrocatalytic deuterium labelling via radical H/D exchange | Nature Catalysis

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Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript. Advertisement Nature Catalysis (2025)Cite this article Deuterium labelling has widespread applications in medicinal chemistry, chemical science and materials science. Hydrogen isotope exchange for deuterium labelling of C(sp3)–H bonds under mild conditions remains a key challenge in labelling reactions. Here we show an electrocatalytic strategy enabling rapid (<10 min) deuteration of natural products and pharmaceuticals. Using clusters containing boron, (TBA)2B10H10, as the electrocatalyst, anodically generated [B10H10]•− intermediates undergo hydrogen-atom transfer with C(sp3)–H/D bonds, forming stabilized [B10H10H/D]− sp

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